Chemical or scientific names are used to give an accurate description of a substance's composition. It is able to attack glass, concrete, metals, organic matter. [22] Some solid nonmetals (sulfur, phosphorus) react vigorously in liquid fluorine. [61][62][63][64][65] Fluorapatite (Ca5(PO4)3F), which contains most of the world's fluoride, is an inadvertent source of fluoride as a byproduct of fertilizer production. [202][203][204] Fluoroelastomers such as Viton are crosslinked fluoropolymer mixtures mainly used in O-rings;[200] perfluorobutane (C4F10) is used as a fire-extinguishing agent. [104][105][106], Covalent bonding first comes to prominence in the tetrafluorides: those of zirconium, hafnium[107][108] and several actinides[109] are ionic with high melting points,[110][note 12] while those of titanium,[113] vanadium,[114] and niobium are polymeric,[115] melting or decomposing at no more than 350 °C (660 °F). These thirteen are those of molybdenum, technetium, ruthenium, rhodium, tungsten, rhenium, osmium, iridium, platinum, polonium, uranium, neptunium, and plutonium. [163] Polytetrafluoroethylene (PTFE), the simplest fluoropolymer and perfluoro analogue of polyethylene with structural unit –CF2–, demonstrates this change as expected, but its very high melting point makes it difficult to mold. [79][173] Regulator valves and pipework are made of nickel, the latter possibly using Monel instead. [287] An outlier is HFO-1234yf which is a new type of refrigerant called a Hydrofluoroolefin (HFO) and has attracted global demand due to its GWP of less than 1 compared to 1,430 for the current refrigerant standard HFC-134a. Recently, the fuel cell application has reemerged with efforts to install proton exchange membrane fuel cells into automobiles. This Site Might Help You. In the laboratory, glassware may carry fluorine gas under low pressure and anhydrous conditions;[174] some sources instead recommend nickel-Monel-PTFE systems. Log in Sign up. [30] Although nitrogen trifluoride is stable, nitrogen requires an electric discharge at elevated temperatures for reaction with fluorine to occur, due to the very strong triple bond in elemental nitrogen;[31] ammonia may react explosively. Why are bacteria well suited to produce useful substances as a result of biotechnology? Germany used high-temperature electrolysis to make tons of the planned incendiary chlorine trifluoride[94] and the Manhattan Project used huge quantities to produce uranium hexafluoride for uranium enrichment. The IUPAC name of $\ce{K4[Fe(CN)6]}$ is:. What is the distrbution of water in the lithosphere? How old was Ralph macchio in the first Karate Kid? Note: The metal atom or ion is writtenbefore the ligands in the chemical formula. [23] Hydrogen sulfide[23] and sulfur dioxide[24] combine readily with fluorine, the latter sometimes explosively; sulfuric acid exhibits much less activity, requiring elevated temperatures. It functions as a Lewis acid and combines with Lewis bases like ammonia to form adducts. [25], Hydrogen, like some of the alkali metals, reacts explosively with fluorine. Partial and complete lung filling have been considered, though only the former has had any significant tests in humans. [290][291][292] PFAAs have been found in trace quantities worldwide from polar bears to humans, with PFOS and PFOA known to reside in breast milk and the blood of newborn babies. [79][91][92], Large-scale production of elemental fluorine began during World War II. Alkali metals cause explosions and alkaline earth metals display vigorous activity in bulk; to prevent passivation from the formation of metal fluoride layers, most other metals such as aluminium and iron must be powdered,[19] and noble metals require pure fluorine gas at 300–450 °C (575–850 °F). [194], About 30% of agrichemicals contain fluorine,[208] most of them herbicides and fungicides with a few crop regulators. About 20% of manufactured HF is a byproduct of fertilizer production, which produces hexafluorosilicic acid (H2SiF6), which can be degraded to release HF thermally and by hydrolysis: Moissan's method is used to produce industrial quantities of fluorine, via the electrolysis of a potassium fluoride/hydrogen fluoride mixture: hydrogen and fluoride ions are reduced and oxidized at a steel container cathode and a carbon block anode, under 8–12 volts, to generate hydrogen and fluorine gas respectively. [266][271], Soluble fluorides are moderately toxic: 5–10 g sodium fluoride, or 32–64 mg fluoride ions per kilogram of body mass, represents a lethal dose for adults. [262] It is a volatile liquid due to the presence of hydrogen bonding (while the other hydrohalic acids are gases).
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